{"id":8961,"date":"2025-04-02T18:58:53","date_gmt":"2025-04-02T10:58:53","guid":{"rendered":"https:\/\/www.dmp-30.cn\/archives\/8961"},"modified":"2025-04-02T18:58:53","modified_gmt":"2025-04-02T10:58:53","slug":"%e6%88%b7%e5%a4%96%e8%a3%85%e5%a4%87%e4%b8%ad%e7%9a%84%e9%ab%98%e7%a8%b3%e5%ae%9a%e6%80%a7%e8%a7%a3%e5%86%b3%e6%96%b9%e6%a1%88%ef%bc%9a%e4%b8%89%e8%8b%af%e5%9f%ba%e7%a3%b7%e7%9a%84%e6%a1%88%e4%be%8b","status":"publish","type":"post","link":"https:\/\/www.dmp-30.cn\/archives\/8961","title":{"rendered":"\u6237\u5916\u88c5\u5907\u4e2d\u7684\u9ad8\u7a33\u5b9a\u6027\u89e3\u51b3\u65b9\u6848\uff1a\u4e09\u82ef\u57fa\u78f7\u7684\u6848\u4f8b\u7814\u7a76"},"content":{"rendered":"
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\u4e09\u57fa\u78f7\u662f\u4e00\u79cd\u6709\u673a\u78f7\u5316\u5408\u7269\uff0c\u5206\u5b50\u5f0f\u4e3aC18H15P\uff0c\u5176\u72ec\u7279\u7684\u5316\u5b66\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u4f18\u5f02\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\u3002\u8fd9\u79cd\u5316\u5408\u7269\u4e0d\u4ec5\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5de5\u4e1a\u9886\u57df\uff0c\u8fd8\u5728\u6237\u5916\u88c5\u5907\u7684\u7814\u53d1\u4e2d\u626e\u6f14\u7740\u4e0d\u53ef\u6216\u7f3a\u7684\u89d2\u8272\u3002\u4ece\u9632\u6c34\u6d82\u5c42\u5230\u8010\u78e8\u6750\u6599\uff0c\u518d\u5230\u6297\u7d2b\u5916\u7ebf\u529f\u80fd\u5c42\uff0c\u4e09\u57fa\u78f7\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\u3002\u5b83\u7684\u5b58\u5728\u8ba9\u88c5\u5907\u66f4\u52a0\u8010\u7528\u3001\u8f7b\u4fbf\u4e14\u73af\u4fdd\uff0c\u771f\u6b63\u5b9e\u73b0\u4e86\u79d1\u6280\u4e0e\u81ea\u7136\u7684\u5b8c\u7f8e\u7ed3\u5408\u3002<\/p>\n
\u672c\u6587\u5c06\u6df1\u5165\u63a2\u8ba8\u4e09\u57fa\u78f7\u5728\u6237\u5916\u88c5\u5907\u4e2d\u7684\u5e94\u7528\u53ca\u5176\u5e26\u6765\u7684\u9ad8\u7a33\u5b9a\u6027\u89e3\u51b3\u65b9\u6848\u3002\u901a\u8fc7\u6848\u4f8b\u5206\u6790\u548c\u591a\u7ef4\u5ea6\u5bf9\u6bd4\uff0c\u6211\u4eec\u5c06\u63ed\u793a\u8fd9\u4e00\u795e\u5947\u5316\u5408\u7269\u5982\u4f55\u6539\u53d8\u6237\u5916\u88c5\u5907\u7684\u8bbe\u8ba1\u7406\u5ff5\uff0c\u5e76\u4e3a\u63a2\u9669\u8005\u63d0\u4f9b\u66f4\u53ef\u9760\u7684\u4fdd\u969c\u3002\u540c\u65f6\uff0c\u6211\u4eec\u8fd8\u5c06\u5f15\u7528\u56fd\u5185\u5916\u76f8\u5173\u6587\u732e\uff0c\u7528\u8be6\u5b9e\u7684\u6570\u636e\u548c\u4e25\u8c28\u7684\u903b\u8f91\u4e3a\u8bfb\u8005\u5448\u73b0\u4e00\u573a\u79d1\u5b66\u4e0e\u827a\u672f\u4ea4\u7ec7\u7684\u77e5\u8bc6\u76db\u5bb4\u3002\u63a5\u4e0b\u6765\uff0c\u8bf7\u8ddf\u968f\u6211\u4eec\u4e00\u8d77\u8d70\u8fdb\u4e09\u57fa\u78f7\u7684\u5947\u5999\u4e16\u754c\u5427\uff01<\/p>\n
\u4e09\u57fa\u78f7\uff08Triphenylphosphine, TPP\uff09\u662f\u4e00\u79cd\u7531\u4e09\u4e2a\u73af\u4e0e\u4e00\u4e2a\u78f7\u539f\u5b50\u7ec4\u6210\u7684\u6709\u673a\u78f7\u5316\u5408\u7269\uff0c\u5176\u5206\u5b50\u5f0f\u4e3aC18H15P\u3002\u4f5c\u4e3a\u4e00\u79cd\u5178\u578b\u7684\u8def\u6613\u65af\u78b1\uff0c\u4e09\u57fa\u78f7\u5177\u6709\u9ad8\u5ea6\u7684\u7535\u5b50\u4f9b\u7ed9\u80fd\u529b\uff0c\u8fd9\u4f7f\u5176\u80fd\u591f\u4e0e\u5176\u4ed6\u5316\u5408\u7269\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u4f4d\u952e\u3002\u6b64\u5916\uff0c\u4e09\u57fa\u78f7\u8fd8\u5c55\u73b0\u51fa\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3001\u5316\u5b66\u60f0\u6027\u4ee5\u53ca\u6eb6\u89e3\u6027\uff0c\u8fd9\u4e9b\u7279\u6027\u4f7f\u5b83\u5728\u591a\u4e2a\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u3002<\/p>\n
\u4e09\u57fa\u78f7\u7684\u5206\u5b50\u7ed3\u6784\u975e\u5e38\u72ec\u7279\uff0c\u5176\u4e2d\u78f7\u539f\u5b50\u88ab\u4e09\u4e2a\u73af\u5305\u56f4\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u5e73\u9762\u4e09\u89d2\u5f62\u7684\u51e0\u4f55\u6784\u578b\u3002\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86\u4e09\u57fa\u78f7\u6781\u9ad8\u7684\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u5176\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u4ee5\u4e0b\u662f\u4e09\u57fa\u78f7\u7684\u4e00\u4e9b\u57fa\u672c\u7269\u7406\u53c2\u6570\uff1a<\/p>\n
\u53c2\u6570<\/strong><\/th>\n\u6570\u503c<\/strong><\/th>\n<\/tr>\n<\/thead>\n\n | \u5206\u5b50\u91cf<\/td>\n | 262.29 g\/mol<\/td>\n<\/tr>\n | \u5916\u89c2<\/td>\n | \u767d\u8272\u6216\u6de1\u9ec4\u8272\u6676\u4f53<\/td>\n<\/tr>\n | \u7194\u70b9<\/td>\n | 80-83\u00b0C<\/td>\n<\/tr>\n | \u6cb8\u70b9<\/td>\n | >300\u00b0C\uff08\u5206\u89e3\uff09<\/td>\n<\/tr>\n | \u5bc6\u5ea6<\/td>\n | 1.14 g\/cm\u00b3<\/td>\n<\/tr>\n | \u6eb6\u89e3\u6027<\/td>\n | \u5fae\u6eb6\u4e8e\u6c34\uff0c\u53ef\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n | \u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u4e09\u57fa\u78f7\u867d\u7136\u672c\u8eab\u4e0d\u6eb6\u4e8e\u6c34\uff0c\u4f46\u53ef\u4ee5\u4e0e\u67d0\u4e9b\u91d1\u5c5e\u79bb\u5b50\u6216\u6709\u673a\u5316\u5408\u7269\u5f62\u6210\u53ef\u6eb6\u7684\u914d\u5408\u7269\uff0c\u8fd9\u4e00\u7279\u6027\u4e3a\u5176\u5728\u529f\u80fd\u6027\u6750\u6599\u4e2d\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n \u4f5c\u7528\u673a\u5236<\/h3>\n\u4e09\u57fa\u78f7\u7684\u4e3b\u8981\u4f5c\u7528\u673a\u5236\u5728\u4e8e\u5176\u4f5c\u4e3a\u914d\u4f53\u7684\u80fd\u529b\u3002\u5b83\u53ef\u4ee5\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\uff08\u5982\u94af\u3001\u954d\u7b49\uff09\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\uff0c\u8fd9\u4e9b\u914d\u5408\u7269\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u5728\u6237\u5916\u88c5\u5907\u7684\u9632\u6c34\u6d82\u5c42\u5236\u9020\u8fc7\u7a0b\u4e2d\uff0c\u4e09\u57fa\u78f7\u5e38\u88ab\u7528\u4f5c\u50ac\u5316\u5242\uff0c\u4fc3\u8fdb\u7845\u6c27\u70f7\u4ea4\u8054\u53cd\u5e94\u7684\u53d1\u751f\u3002\u901a\u8fc7\u8fd9\u79cd\u65b9\u5f0f\uff0c\u6d82\u5c42\u6750\u6599\u80fd\u591f\u5f62\u6210\u81f4\u5bc6\u7684\u7f51\u7edc\u7ed3\u6784\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u5176\u9632\u6c34\u6027\u80fd\u3002<\/p>\n \u6b64\u5916\uff0c\u4e09\u57fa\u78f7\u8fd8\u5177\u5907\u6297\u6c27\u5316\u548c\u7d2b\u5916\u5438\u6536\u7684\u529f\u80fd\u3002\u7531\u4e8e\u5176\u5206\u5b50\u4e2d\u542b\u6709\u82b3\u9999\u73af\u7ed3\u6784\uff0c\u4e09\u57fa\u78f7\u80fd\u591f\u6709\u6548\u6355\u83b7\u81ea\u7531\u57fa\u5e76\u6291\u5236\u5149\u964d\u89e3\u53cd\u5e94\u7684\u53d1\u751f\u3002\u8fd9\u610f\u5473\u7740\uff0c\u5728\u6237\u5916\u88c5\u5907\u4e2d\u6dfb\u52a0\u9002\u91cf\u7684\u4e09\u57fa\u78f7\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u5ef6\u957f\u6750\u6599\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u8fd8\u80fd\u589e\u5f3a\u5176\u5bf9\u6076\u52a3\u73af\u5883\u7684\u9002\u5e94\u80fd\u529b\u3002<\/p>\n \u5e94\u7528\u4f18\u52bf<\/h3>\n\u7efc\u4e0a\u6240\u8ff0\uff0c\u4e09\u57fa\u78f7\u51ed\u501f\u5176\u72ec\u7279\u7684\u5316\u5b66\u7279\u6027\u548c\u5e7f\u6cdb\u7684\u9002\u7528\u8303\u56f4\uff0c\u5df2\u6210\u4e3a\u6237\u5916\u88c5\u5907\u7814\u53d1\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u91cd\u8981\u6750\u6599\u3002\u4e0b\u4e00\u8282\uff0c\u6211\u4eec\u5c06\u8fdb\u4e00\u6b65\u63a2\u8ba8\u5b83\u5728\u5177\u4f53\u4ea7\u54c1\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n \n \u4e09\u57fa\u78f7\u5728\u6237\u5916\u88c5\u5907\u4e2d\u7684\u5177\u4f53\u5e94\u7528<\/h2>\n\u5982\u679c\u8bf4\u4e09\u57fa\u78f7\u662f\u6237\u5916\u88c5\u5907\u9886\u57df\u7684\u201c\u8d85\u7ea7\u660e\u661f\u201d\uff0c\u90a3\u4e48\u5b83\u7684\u821e\u53f0\u5c31\u662f\u90a3\u4e9b\u9700\u8981\u6781\u81f4\u7a33\u5b9a\u6027\u7684\u9ad8\u6027\u80fd\u4ea7\u54c1\u3002\u4ece\u767b\u5c71\u9774\u5230\u5e10\u7bf7\u5e03\u6599\uff0c\u4ece\u6ed1\u96ea\u677f\u5230\u9632\u98ce\u8863\uff0c\u4e09\u57fa\u78f7\u4ee5\u5176\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\u4e3a\u8fd9\u4e9b\u88c5\u5907\u6ce8\u5165\u4e86\u5f3a\u5927\u7684\u751f\u547d\u529b\u3002\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u5c06\u9010\u4e00\u5256\u6790\u4e09\u57fa\u78f7\u5728\u4e0d\u540c\u7c7b\u578b\u6237\u5916\u88c5\u5907\u4e2d\u7684\u5177\u4f53\u5e94\u7528\uff0c\u5e26\u60a8\u9886\u7565\u5b83\u7684\u975e\u51e1\u9b45\u529b\u3002<\/p>\n \u767b\u5c71\u9774\uff1a\u811a\u5e95\u7684\u201c\u5b88\u62a4\u5929\u4f7f\u201d<\/h3>\n\u767b\u5c71\u9774\u4f5c\u4e3a\u6237\u5916\u8fd0\u52a8\u7684\u6838\u5fc3\u88c5\u5907\u4e4b\u4e00\uff0c\u5176\u8212\u9002\u6027\u3001\u8010\u7528\u6027\u548c\u6293\u5730\u529b\u76f4\u63a5\u5173\u7cfb\u5230\u63a2\u9669\u8005\u7684\u5b89\u5168\u3002\u800c\u4e09\u57fa\u78f7\u5728\u8fd9\u91cc\u7684\u4f5c\u7528\u53ef\u8c13\u529f\u4e0d\u53ef\u6ca1\u3002\u901a\u8fc7\u4e0e\u805a\u6c28\u916f\uff08PU\uff09\u6750\u6599\u7ed3\u5408\uff0c\u4e09\u57fa\u78f7\u53ef\u4ee5\u663e\u8457\u63d0\u5347\u978b\u5e95\u7684\u8010\u78e8\u6027\u548c\u6297\u6495\u88c2\u5f3a\u5ea6\u3002\u6b64\u5916\uff0c\u5b83\u8fd8\u80fd\u6539\u5584\u978b\u5e95\u6750\u6599\u7684\u67d4\u97e7\u6027\uff0c\u4f7f\u5f97\u767b\u5c71\u9774\u5373\u4f7f\u5728\u5bd2\u51b7\u73af\u5883\u4e2d\u4e5f\u4e0d\u4f1a\u53d8\u5f97\u50f5\u786c\u3002<\/p>\n
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